Fire hazard, reactive, immediate acute health hazard, delayed chronic health hazard. The weight percent of vinyl acetate usually varies from 10 to 40%, with the. Safety and handling considerations to obtain a material safety data sheet msds or sds for vinyl acetate monomer or a safe. Msds of ethylene vinyl acetate emulsion ethylene vinyl acetate emulsion da310 download file pdf.
The weight percent of vinyl acetate usually varies from 10 to 40%, with the remainder being ethylene. Page 6 of 7 msds vinyl acetate monomer no increase in tumour incidence was found in rats administered vinyl acetate in the drinkingwater in utero and then for life. Ethylenevinyl acetate eva, also known as poly ethylenevinyl acetate peva, is the copolymer of ethylene and vinyl acetate. Ethylene vinyl acetate and ethylene vinyl alcohol copolymer. Wear appropriate protective eyeglasses or chemical safety goggles as described by oshas eye and face protection regulations in 29 cfr 1910. Acute exposure to vinyl acetate monomer may require decontamination and life support for the victims. Vinyl acetate monomer safety data sheet international vinyl acetate company safety data sheet according to regulation ec no. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Vinyl acetate vapors are uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in plugging of vents. Divini cultus sanctitatem pdf new pdf download service.
Vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be. Ac183250000, ac183250010, ac183250250, ac183255000 synonyms. Msds sheet flotec inc this msds covers the following products. Vinyl acetate is a colorless, flammable liquid that also has a characteristic smell that can quickly become irritating. Vinyl acetate monomer vam is used for the production of polymer emulsions of various types, which are base resins for waterbased paints, adhesives, paper coatings and textile finishes. Containers of this material may be hazardous when empty since they retain product residues dust, solids. Vinyl acetate monomer vam vinyl acetate acetic acid, vinyl. Fire hazard, reactive, immediate acute health hazard. File type icon file name description size revision time user. We offer halal and kosher polyvinyl acetate made in an. Msds of ethylene vinyl acetate emulsion ethylene vinyl acetate emulsion da128h download file pdf. When handled properly, vam can be stored, transported and otherwise managed safely.
Monitor inhibitor to maintain appropriate concentration. Import data and price of vinyl acetate monomer zauba. Revised october 24, 2006 flexible vinyl page 1 of 3 msds material safety data sheet i. Ethylene vinyl acetate copolymers are used to produce flexible films, coatings, adhesives, moldings and insulation. These polymers are the base for many industrial and. Broadly speaking, there are three different types of eva copolymer, which differ in the vinyl acetate va content. Astm d559418a, standard test method for determination of the vinyl acetate content of ethylene vinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir, astm international, west conshohocken, pa, 2018. Your new online msds binder is a place for you to store the material safety data sheets. Vinyl acetate monomer vam is a highvolume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. Other companies are charging thousands of dollars to. These polymers are the base for many industrial and consumer products as well as for other polymers.
Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate esters. This monomer is used principally in the production of polyvinyl acetate pvac and other vinyl acetate copolymers. Material safety data sheet msds vinyl acetate monomer s. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. The basis for the proposed limits is an epidemiologic report by deese and joyner 1969ex. Revised october 24, 2006 flexible vinyl msds material. Apr 27, 2020 emulsogen lcn 407 is used as nonionic emulsifier for the emulsion polymerization of monomers like acrylates, styreneacrylates and vinyl acetate. Inhalation of vapors may result in dizziness or suffocation. Revised october 24, 2006 flexible vinyl msds material safety. Vinyl acetate is the acetate ester of vinyl alcohol.
Wear appr opriate personal protective equipment as specified in section 8. The substance identity section is calculated from substance identification information from all echa databases. Material safety data sheet according to 19072006ec, article 31. Vinyl acetate monomer safety data sheet international. Us2431554a purification of vinyl acetate by distillation.
Material safety data sheet ehylene vinyl acetate copolymer section 1 product and company identification manufacturer. Hazard statements h225 highly flammable liquid and vapour. Ethylene vinyl acetate, free ethylene vinyl acetate software downloads, page 2. Acrylonitrile vinyl acetate copolymer 24980629 0100. Polyvinyl acetate is a precursor of polyvinilyc alcohol and polyvinyl acetate resins pva.
Material safety data sheet according to 19072006ec, article 31 2. Ethylene vinyl acetate eva copolymer, another commercially available thermoplastic has broad industrial applications, ranging from hot melt adhesive to wine bottle closures and cable sheathing. Biodegradability of polyvinyl acetate and related polymers article pdf available in advances in polymer science 245. Sep 28, 2011 vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. Astm d5594 18a standard test method for determination of. First, data was generated from the simulation of vinyl acetate monomer process. Accidental release measures ventilate area of leak or spill. Vam can be polymerized in mass, solution, suspension or emulsion. The aim was to develop a suitable control model and then its performance was analyzed. Show this safety data sheet to the doctor in attendance. Product and company information hoehn plastics inc.
As a practical illustration, a vinyl acetate monomer plant was considered. Ethylene vinyl acetate eva, also known as poly ethylene vinyl acetate peva, is the copolymer of ethylene and vinyl acetate. Keep polyvinyl acetate in a well closed container stored under cold to warm conditions, 2 to 40 c, 36 to 104f in a ventilated area. Information concerning particular hazards for human and environment. View detailed import data, price, monthly trends, major importing countries, major ports of vinyl acetate monomer.
Material safety data sheet of vinyl acetate monomer. Pp102d tenite cellulose acetate butyrate chemical resistance. Vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. Material safety data sheet poly vinyl acetate, average m. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Sigmaaldrich offers a number of vinyl acetate products. Signs and symptoms of acute vinyl acetate monomer exposure. Astm d559418a, standard test method for determination of the vinyl acetate content of ethylenevinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir, astm international.
A wide variety of msds vinyl acetate options are available to you, such as grade. Ethylene vinyl acetate software free download ethylene. The hazard classification and labelling section shows the hazards of a substance based on the standardised system of statements. Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate. Material safety data sheet according to 19072006ec. Other applications are coatings for textile and paper industries, laminated. Aug 25, 2017 vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. Emulsogen lcn 407 is used as nonionic emulsifier for the emulsion polymerization of monomers like acrylates, styreneacrylates and vinyl acetate. Pdf biodegradability of polyvinyl acetate and related. Vinyl acetate monomer vam is a high volume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. Container headspace may contain vinyl acetate monomer vapors.
Material safety data sheet polyvinyl acetate, average m. A wide variety of msds vinyl acetate options are available to you, such as grade standard. Ethylene vinyl alcohol can be used to produce gas barrier layers in coextruded packaging. Vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst.
Polyvinyl acetate sds ghs, msds sheet of manufacturers. The chemical formula for vinyl acetate isc h o, and its molecular weight is 86. Eva is commercially available with vinyl acetate vac content varying from 3 to 50%. Vinyl acetate monomer may irritate the skin, eyes, and respiratory tract. This monomer is used principally in the production of polyvinyl acetate pvac and other. Lamination of glass for decorative or functional use.
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